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Face-in-palm-sigh is when you're so fed up with a conversation or situation you're tempted to punch the person and then go to bed with a headache.
My mom tried to explain her dating life for 2 hours. I did the face-in-palm-sigh and fell asleep mid-sentence.
My boss just said 'we’re doing this again' and I did the face-in-palm-sigh so hard I got a crick in my neck.
My friend kept talking about his ex for 10 minutes. I did the face-in-palm-sigh and texted him 'just end it already'.